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Why
is stainless steel stainless? Stainless steels are defined as being characterized
by particularly high resistance to chemical attack by aqueous media. In general,
they contain at least 12% by weight of chrome and a maximum of 1.2% carbon. The
reason of their high resistance to corrosion is a passive layer that forms on
the surface. This consists of a metal oxide or hydroxide layer, rich in chrome,
only a few Angstrom units thick, separating the actual metal from the attacking
medium.
History
of stainless steel Steel is made corrosion-resistant by the addition
of nickel and chromium. This fact was known as long ago as the 19th century, but
at the time the steels alloyed in this way still left a great deal to be desired.
The breakthrough was made by Krupp in 1912. In addition to establishing the ideal
nickel to chromium ratio to guarantee high corrosion resistance, the company also
discovered that precisely controlled heat treatment decisively improved the mechanical
properties of the material. This innovation opened up completely new perspectives
for fabrication and laid the foundation stone for the success of stainless steel.
Today stainless steel is continuous optimization and the emergence of new applications
ensure a shining future for this multipurpose material.
Types
of stainless steel There are five basic categories of stainless steel,
Austenitic, Ferritic, Martensitic, Duplex and Precipitation Hardening. The
austenitic grades are non magnetic and in addition to chromium, typically at the
18% level, contain nickel which increases corrosion resistance. They are the most
widely used group of stainless steels. The ferritic grades are magnetic, have
contain chromium as the main element, typically at the 17% level. They have good
oxidation resistance. The martensitic grades are magnetic, containing typically
13% chromium and a moderate level of carbon. They are hardenable by quenching
and tempering. The deplex grades have a mixed structure of Ferritic and Austenitic,
chromium content varies from 18% to 28% and nickel from 4.5% to 8%. They find
application particularly where high chloride content is present. The precipitation
hardening grades have chromium content at 17% typically with additions of nickel,
copper and niobium. They can be hardened in a single ageing process.
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